Proton-induced reactivities of ruthenium azido complexes: the first example of boron-carbon bond formation by methylene insertion into a B-H bond.

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Title:	Proton-induced reactivities of ruthenium azido complexes: the first example of boron-carbon bond formation by methylene insertion into a B-H bond.
Authors:	Yih-Hsing Lo Han-Gung Chen Ting Shen Kuo 羅義興
Contributors:	臺北市立教育大學應用物理暨化學系
Date:	2011
Issue Date:	2011-12-01 10:55:48 (UTC+8)
Abstract:	Whereas the reaction of Tp(PhCN)(PPh(3))Ru-N(3) Tp = HB(pz)(3), pz = pyrazolyl with CH(3)I in CH(2)Cl(2) led to the cationic ruthenium methyleneimine complex the analogous reaction with HCl gave rise to the ruthenium chloride complex containing a methyl tris(pyrazolyl)borate ligand (Me)Tp(PPh(3))(PhCN)RuCl, as a result of the highly unusual methylene insertion into a B-H bond of the Tp ligand.
Relation:	Dalton Transactions Volume: 40, Issue: 12 Pages: 2711-2715
Appears in Collections:	[Department of Applied Physics and Chemistry] Periodical Articles

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