University of Taipei:Item 987654321/2580
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    Please use this identifier to cite or link to this item: http://utaipeir.lib.utaipei.edu.tw/dspace/handle/987654321/2580


    Title: Alloying of Co ultrathin films on Pt(111) with Ag buffer layers
    Authors: Shern, C. S.
    Su, C. W.
    Wu, Y. E.
    Fu, T. Y.
    何慧瑩
    Contributors: 臺北市立教育大學自然科學系
    Keywords: cobalt
    silver
    platinum
    surface alloying
    interface structure
    chemical interdiffusion
    low energy electron diffraction
    ultraviolet photoelectron spectra
    Auger electron spectra
    monolayers
    cobalt alloys
    platinum alloys
    free energy
    surface energy
    Date: 2000
    Issue Date: 2009-07-27 15:18:29 (UTC+8)
    Abstract: The structure at the interfaces of Co/Ag/Pt(111) was studied by low-energy electron diffraction, ultraviolet photoelectron spectroscopy, Auger electron spectroscopy, and depth profiling. An atomic exchange occurs between Co and Ag before the formation of a Co-Pt alloy. Ag atoms start moving to the top at 425 K when the coverage of Co is one monolayer. The temperature of the complete exchange between Ag atoms and Co atoms is dependent on the thickness of the Ag buffer layer. The Co-Pt alloy develops after the atomic exchange is complete. The especially small surface free energy of Ag and large strain energy in this system are proposed as the driving force for the exchange.
    Relation: Journal of Applied Physics, V88(2), p.705-709
    Appears in Collections:[Department of Applied Physics and Chemistry] Periodical Articles

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